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The Reaction of Hydrogen Halides with Tetrahydroborate Anion and Hexahydro-closo-hexaborate Dianion
The mechanism of the consecutive halogenation of the tetrahydroborate anion [BH(4)](−) by hydrogen halides (HX, X = F, Cl, Br) and hexahydro-closo-hexaborate dianion [B(6)H(6)](2−) by HCl via electrophile-induced nucleophilic substitution (EINS) was established by ab initio DFT calculations [M06/6-3...
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| Publicado no: | Molecules |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
MDPI
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8235096/ https://ncbi.nlm.nih.gov/pubmed/34202981 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26123754 |
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