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Synthetic Studies towards the Hamigerans with a 6-7-5 Tricyclic Core

An approach towards the 6-7-5 tricyclic carbon skeleton of the hamigeran natural products was developed. The key steps include a benzyne-β-ketoester annulative ring expansion to form the 7-membered ring, a Nazarov reaction to form the 5-membered ring, a Ni-catalyzed conjugate methyl addition or a Co...

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Bibliographic Details
Published in:Org Lett
Main Authors: Jiang, Baiyang, Dai, Mingji
Format: Artigo
Language:Inglês
Published: 2020
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8232352/
https://ncbi.nlm.nih.gov/pubmed/32401527
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01253
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