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Density Functional Theory Guide for an Allyl Monomer Polymerization Mechanism: Photoinduced Radical-Mediated [3 + 2] Cyclization

[Image: see text] Polymerization of allyl ether monomers has previously been considered a free-radical addition polymerization mechanism, but it is difficult to achieve because of the high electron density of their double bond. To interpret the mechanism of photopolymerization, we therefore proposed...

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Detalhes bibliográficos
Publicado no:ACS Omega
Main Authors: Zhao, Xiaotian, Huang, Wanqiu, Lin, Shibo, Chen, Xi, Guo, Xirui, Zou, Dehong, Ye, Guodong
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2021
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8223207/
https://ncbi.nlm.nih.gov/pubmed/34179605
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.1c00165
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