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Nitrile Oxidation at a Ruthenium Complex leading to Intermolecular Imido Group Transfer
The oxidation of an acetonitrile ligand coordinated to ruthenium is explored in deuterated dimethylsulfoxide by (1)H NMR spectroscopy. When oxidized with an iodosoarene oxygen atom transfer (OAT) reagent, kinetic studies demonstrate that the nitrile ligand does not dissociate before reacting. Instea...
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| Publicado en: | Organometallics |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8216214/ https://ncbi.nlm.nih.gov/pubmed/34163095 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.0c00589 |
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