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Chemical tuning of spin clock transitions in molecular monomers based on nuclear spin-free Ni(ii)
We report the existence of a sizeable quantum tunnelling splitting between the two lowest electronic spin levels of mononuclear Ni complexes. The level anti-crossing, or magnetic “clock transition”, associated with this gap has been directly monitored by heat capacity experiments. The comparison of...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179637/ https://ncbi.nlm.nih.gov/pubmed/34168771 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05856d |
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