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Redox-induced reversible [2 + 2] cycloaddition of an etheno-fused diporphyrin

3,5-Ethenoporphyrin is a π-extended porphyrin containing a fused ethene unit between the meso- and β-positions, exhibiting unique contribution of macrocyclic antiaromaticity. We have recently reported that its analogue, etheno-fused diporphyrin, underwent thermal [2 + 2] cycloaddition to furnish X-s...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Miyagawa, Kazuya, Hisaki, Ichiro, Fukui, Norihito, Shinokubo, Hiroshi
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179634/
https://ncbi.nlm.nih.gov/pubmed/34168775
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00438g
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