Exploiting host–guest chemistry to manipulate magnetic interactions in metallosupramolecular M(4)L(6) tetrahedral cages

Reaction of Ni(OTf)(2) with the bisbidentate quaterpyridine ligand L results in the self-assembly of a tetrahedral, paramagnetic cage [Ni(II)(4)L(6)](8+). By selectively exchanging the bound triflate from [OTf⊂Ni(II)(4)L(6)](OTf)(7) (1), we have been able to prepare a series of host–guest complexes...

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Bibliografische gegevens
Gepubliceerd in:Chem Sci
Hoofdauteurs: Scott, Aaron J., Vallejo, Julia, Sarkar, Arup, Smythe, Lucy, Regincós Martí, E., Nichol, Gary S., Klooster, Wim T., Coles, Simon J., Murrie, Mark, Rajaraman, Gopalan, Piligkos, Stergios, Lusby, Paul J., Brechin, Euan K.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: The Royal Society of Chemistry 2021
Onderwerpen:
Chemistry
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179613/
https://ncbi.nlm.nih.gov/pubmed/34168772
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00647a
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