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An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO(2)-to-CO reduction at low overpotential

The [fac-Mn(bpy)(CO)(3)Br] complex is capable of catalyzing the electrochemical reduction of CO(2) to CO with high selectivity, moderate activity and large overpotential. Several attempts have been made to lower the overpotential and to enhance the catalytic activity of this complex by manipulating...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chem Sci
Egile Nagusiak: Yang, Yong, Ertem, Mehmed Z., Duan, Lele
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: The Royal Society of Chemistry 2021
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179605/
https://ncbi.nlm.nih.gov/pubmed/34168756
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05679k
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