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Nickel-catalyzed asymmetric reductive arylation of α-chlorosulfones with aryl halides

We report an asymmetric Ni-catalyzed reductive cross-coupling of aryl/heteroaryl halides with racemic α-chlorosulfones to afford enantioenriched sulfones. The reaction tolerates a variety of functional groups under mild reaction conditions, which complements the current methods. The utility of this...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Sun, Deli, Ma, Guobin, Zhao, Xinluo, Lei, Chuanhu, Gong, Hegui
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: The Royal Society of Chemistry 2021
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179603/
https://ncbi.nlm.nih.gov/pubmed/34168777
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00283j
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