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Modulating the radical reactivity of phenyl radicals with the help of distonic charges: it is all about electrostatic catalysis

This manuscript reports the modulation of H-abstraction reactivity of phenyl radicals by (positive and negative) distonic ions. Specifically, we focus on the origins of this modulating effect: can the charged functional groups truly be described as “extreme forms of electron-withdrawing/donating sub...

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Detaylı Bibliyografya
Yayımlandı:Chem Sci
Asıl Yazarlar: Mondal, Totan, Shaik, Sason, Kenttämaa, Hilkka, Stuyver, Thijs
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: The Royal Society of Chemistry 2021
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179573/
https://ncbi.nlm.nih.gov/pubmed/34163733
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc07111k
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