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On the location of Lewis acidic aluminum in zeolite mordenite and the role of framework-associated aluminum in mediating the switch between Brønsted and Lewis acidity

Lewis acidic aluminum in zeolites, particularly acidity that is inherent to the framework, is an indeterminate concept. A fraction of framework aluminum changes geometry to octahedral coordination in the proton form of zeolite mordenite. Such octahedrally coordinated aluminum is the precursor of a L...

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Publicat a:Chem Sci
Autors principals: Ravi, Manoj, Sushkevich, Vitaly L., van Bokhoven, Jeroen A.
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2021
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179490/
https://ncbi.nlm.nih.gov/pubmed/34163680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06130a
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