Correlating axial and equatorial ligand field effects to the single-molecule magnet performances of a family of dysprosium bis-methanediide complexes

Treatment of the new methanediide–methanide complex [Dy(SCS)(SCSH)(THF)] (1Dy, SCS = {C(PPh(2)S)(2)}(2−)) with alkali metal alkyls and auxillary ethers produces the bis-methanediide complexes [Dy(SCS)(2)][Dy(SCS)(2)(K(DME)(2))(2)] (2Dy), [Dy(SCS)(2)][Na(DME)(3)] (3Dy) and [Dy(SCS)(2)][K(2,2,2-crypta...

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Publicado en:Chem Sci
Autores principales: Thomas-Hargreaves, Lewis R., Giansiracusa, Marcus J., Gregson, Matthew, Zanda, Emanuele, O'Donnell, Felix, Wooles, Ashley J., Chilton, Nicholas F., Liddle, Stephen T.
Formato: Artigo
Lenguaje:Inglês
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179472/
https://ncbi.nlm.nih.gov/pubmed/34163660
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00238d
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