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Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

Metal–organic frameworks are promising materials for applications such as gas capture, separation, and storage, due to their ability to selectively adsorb small molecules. The metal–organic framework Cu(I)-MFU-4l, which contains coordinatively unsaturated copper(i) centers, can engage in backbonding...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Su, Gregory M., Wang, Han, Barnett, Brandon R., Long, Jeffrey R., Prendergast, David, Drisdell, Walter S.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179296/
https://ncbi.nlm.nih.gov/pubmed/34163980
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06038k
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