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Interplay between spin crossover and proton migration along short strong hydrogen bonds
The iron(ii) salt [Fe(bpp)(2)](isonicNO)(2)·HisonicNO·5H(2)O (1) (bpp = 2,6-bis(pyrazol-3-yl)pyridine; isonicNO = isonicotinate N-oxide anion) undergoes a partial spin crossover (SCO) with symmetry breaking at T(1) = 167 K to a mixed-spin phase (50% high-spin (HS), 50% low-spin (LS)) that is metasta...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
The Royal Society of Chemistry
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179063/ https://ncbi.nlm.nih.gov/pubmed/34163870 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04918b |
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