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Cerium–quinone redox couples put under scrutiny
Homoleptic cerous complexes Ce[N(SiMe(3))(2)](3), [Ce{OSi(OtBu)(3)}(3)](2) and [Ce{OSi(i)Pr(3)}(3)](2) were employed as thermally robust, weakly nucleophilic precursors to assess their reactivity towards 1,4-quinones in non-aqueous solution. The strongly oxidizing quinones 2,3-dichloro-5,6-dicyano-1...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179043/ https://ncbi.nlm.nih.gov/pubmed/34163897 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04489j |
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