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Recent discoveries on the structure of iodine(iii) reagents and their use in cross-nucleophile coupling

This perspective article discusses structural features of iodine(iii) compounds as a prelude to presenting their use as umpolung reagents, in particular as pertains to their ability to promote the selective coupling of two nucleophilic species via 2e(−) oxidation.

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Bibliographische Detailangaben
Veröffentlicht in:Chem Sci
Hauptverfasser: Bauer, Adriano, Maulide, Nuno
Format: Artigo
Sprache:Inglês
Veröffentlicht: The Royal Society of Chemistry 2021
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8178994/
https://ncbi.nlm.nih.gov/pubmed/34163852
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03266b
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