U(2)N@I(h)(7)-C(80): fullerene cage encapsulating an unsymmetrical U(iv)[double bond, length as m-dash]N[double bond, length as m-dash]U(v) cluster

For the first time, an actinide nitride clusterfullerene, U(2)N@I(h)(7)-C(80), is synthesized and fully characterized by X-ray single crystallography and multiple spectroscopic methods. U(2)N@I(h)(7)-C(80) is by far the first endohedral fullerene that violates the well-established tri-metallic nitri...

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Bibliographische Detailangaben
Veröffentlicht in:Chem Sci
Hauptverfasser: Li, Xiaomeng, Roselló, Yannick, Yao, Yang-Rong, Zhuang, Jiaxin, Zhang, Xingxing, Rodríguez-Fortea, Antonio, de Graaf, Coen, Echegoyen, Luis, Poblet, Josep M., Chen, Ning
Format: Artigo
Sprache:Inglês
Veröffentlicht: The Royal Society of Chemistry 2020
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8178745/
https://ncbi.nlm.nih.gov/pubmed/34163596
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04677a
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