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Free-standing metal–organic framework (MOF) monolayers by self-assembly of polymer-grafted nanoparticles

We report a general method for the synthesis of free-standing, self-assembled MOF monolayers (SAMMs) at an air–water interface using polymer-brush coated MOF nanoparticles. UiO-66, UiO-66-NH(2), and MIL-88B-NH(2) were functionalized with a catechol-bound chain-transfer agent (CTA) to graft poly(meth...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Barcus, Kyle, Cohen, Seth M.
Format: Artigo
Language:Inglês
Published: The Royal Society of Chemistry 2020
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163391/
https://ncbi.nlm.nih.gov/pubmed/34123102
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03318a
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