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Enthalpic and entropic contributions to the basicity of cycloalkylamines
Large-ring cycloalkylamines are slightly less basic than other cycloalkylamines such as cyclohexylamine, even though all have tetrahedral carbons and are strain-free. To understand why, enthalpy and entropy for protonation of a series of cycloalkylamines were accurately determined by isothermal titr...
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| Publicado no: | Chem Sci |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8163384/ https://ncbi.nlm.nih.gov/pubmed/34123109 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02931a |
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