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Capture and displacement-based release of the bicarbonate anion by calix[4]pyrroles with small rigid straps

Two-phenoxy walled calix[4]pyrroles 1 and 2 strapped with small rigid linkers containing pyridine and benzene, respectively, have been synthesized. (1)H NMR spectroscopic analyses carried out in CDCl(3) revealed that both of receptors 1 and 2 recognize only F(−) and HCO(3)(−) among various test anio...

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Publicado en:Chem Sci
Main Authors: Heo, Nam Jung, Yang, Ju Ho, Lynch, Vincent M., Ko, Byoung Joon, Sessler, Jonathan L., Kim, Sung Kuk
Formato: Artigo
Idioma:Inglês
Publicado: The Royal Society of Chemistry 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163245/
https://ncbi.nlm.nih.gov/pubmed/34094182
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03445b
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