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Crystal structure and metallization mechanism of the π-radical metal TED
Radical electrons tend to localize on individual molecules, resulting in an insulating (Mott–Hubbard) bandgap in the solid state. Herein, we report the crystal structure and intrinsic electronic properties of the first single crystal of a π-radical metal, tetrathiafulvalene-extended dicarboxylate (T...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Chem Sci |
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| Prif Awduron: | , , , , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
The Royal Society of Chemistry
2020
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8162741/ https://ncbi.nlm.nih.gov/pubmed/34123200 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03521a |
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