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Synthesis of vitisin A & D enabled by a persistent radical equilibrium
The first total synthesis of the resveratrol tetramers vitisin A and vitisin D is reported. Electrochemical generation and selective dimerization of persistent radicals is followed by thermal isomerization of the symmetric C8b–C8c dimer to the C3c–C8b isomer, providing rapid entry into the vitisin c...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8162734/ https://ncbi.nlm.nih.gov/pubmed/32156107 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c01714 |
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