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Combining alkali metals and zinc to harness heterometallic cooperativity in cyclic ester ring-opening polymerisation

Heterometallic cooperativity is an emerging strategy to elevate polymerisation catalyst performance. Here, we report the first heterotrimetallic Na/Zn(2) and K/Zn(2) complexes supported by a ProPhenol ligand, which deliver “best of both” in cyclic ester ring-opening polymerisation, combining the out...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Gruszka, Weronika, Lykkeberg, Anna, Nichol, Gary S., Shaver, Michael P., Buchard, Antoine, Garden, Jennifer A.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162475/
https://ncbi.nlm.nih.gov/pubmed/34123205
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04705h
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