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Synthetic studies toward longeracemine: a SmI(2)-mediated spirocyclization and rearrangement cascade to construct the 2-azabicyclo[2.2.1]heptane framework
Longeracemine, a member of the Daphniphyllum family of alkaloids contains a novel carbon framework featuring a highly functionalized 2-azabicyclo[2.2.1]heptane core as part of an overall 5/6/5/5/6/5 skeleton. A synthetic intermediate containing the core of longeracemine has been efficiently prepared...
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| Vydáno v: | Chem Sci |
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| Hlavní autoři: | , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
The Royal Society of Chemistry
2020
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8162136/ https://ncbi.nlm.nih.gov/pubmed/34094215 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03422c |
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