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Reversible cooperative dihydrogen binding and transfer with a bis-phosphenium complex of chromium
The reversible reaction of H(2) with a bis-phosphenium complex of chromium provides a rare example of 3d transition metal/phosphenium cooperativity. Photolysis induces the activation of H(2) and yields a spectroscopically detectable phosphenium-stabilized (σ–H(2))-complex, readily showing exchange w...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8161683/ https://ncbi.nlm.nih.gov/pubmed/34094222 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03773g |
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