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Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation

A ruthenium-catalyzed ortho C–H arylation process is described using visible light. Using the readily available catalyst [RuCl(2)(p-cymene)](2), visible light irradiation was found to enable arylation of 2-aryl-pyridines at room temperature for a range of aryl bromides and iodides.

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Bibliografiska uppgifter
I publikationen:Chem Sci
Huvudupphovsmän: Sagadevan, Arunachalam, Charitou, Anastasios, Wang, Fen, Ivanova, Maria, Vuagnat, Martin, Greaney, Michael F.
Materialtyp: Artigo
Språk:Inglês
Publicerad: The Royal Society of Chemistry 2020
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159458/
https://ncbi.nlm.nih.gov/pubmed/34122900
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01289k
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