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Large transition state stabilization from a weak hydrogen bond
A series of molecular rotors was designed to study and measure the rate accelerating effects of an intramolecular hydrogen bond. The rotors form a weak neutral O–H⋯O[double bond, length as m-dash]C hydrogen bond in the planar transition state (TS) of the bond rotation process. The rotational barrier...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8159443/ https://ncbi.nlm.nih.gov/pubmed/34123031 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02806a |
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