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Observations of tetrel bonding between sp(3)-carbon and THF

We report the direct observation of tetrel bonding interactions between sp(3)-carbons of the supramolecular synthon 3,3-dimethyl-tetracyanocyclopropane (1) and tetrahydrofuran in the gas and crystalline phase. The intermolecular contact is established via σ-holes and is driven mainly by electrostati...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Heywood, Victoria L., Alford, Thomas P. J., Roeleveld, Julius J., Lekanne Deprez, Siebe J., Verhoofstad, Abraham, van der Vlugt, Jarl Ivar, Domingos, Sérgio R., Schnell, Melanie, Davis, Anthony P., Mooibroek, Tiddo J.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159407/
https://ncbi.nlm.nih.gov/pubmed/34122986
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01559h
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