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An excited state dynamics driven reaction: wavelength-dependent photoisomerization quantum yields in [Ru(bpy)(2)(dmso)(2)](2+)

We report the excited-state behavior of a structurally simple bis-sulfoxide complex, cis-S,S-[Ru(bpy)(2)(dmso)(2)](2+), as investigated by femtosecond pump–probe spectroscopy. The results reveal that a single photon prompts phototriggered isomerization of one or both dmso ligands to yield a mixture...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Livshits, Maksim Y., Wang, Lei, Vittardi, Sebastian B., Ruetzel, Stefan, King, Albert, Brixner, Tobias, Rack, Jeffrey J.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159332/
https://ncbi.nlm.nih.gov/pubmed/34094082
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc00551g
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