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Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(ii)-based porous cages

We describe the synthesis of Fe(ii)-based octahedral coordination cages supported by calixarene capping ligands. The most porous of these molecular cages has an argon accessible BET surface area of 898 m(2) g(−1) (1497 m(2) g(−1) Langmuir). The modular synthesis of molecular cages allows for straigh...

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Publicado en:Chem Sci
Main Authors: Deegan, Meaghan M., Ahmed, Tonia S., Yap, Glenn P. A., Bloch, Eric D.
Formato: Artigo
Idioma:Inglês
Publicado: The Royal Society of Chemistry 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159286/
https://ncbi.nlm.nih.gov/pubmed/34122984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01833c
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