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Synthesis of poly(disulfide)s with narrow molecular weight distributions via lactone ring-opening polymerization

We report the first example of controlled polymerization of poly(disulfide)s with narrow molecular weight distributions. 1,4,5-oxadithiepan-2-one (OTP), a disulfide-containing 7-membered ring lactone, was polymerized by using the diphenylphosphate (DPP) catalyzed lactone ring-opening polymerization...

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Publicado en:Chem Sci
Main Authors: Kim, Sungwhan, Wittek, Kamila I., Lee, Yan
Formato: Artigo
Idioma:Inglês
Publicado: The Royal Society of Chemistry 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159261/
https://ncbi.nlm.nih.gov/pubmed/34122943
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc00834f
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