An iron ketimide single-molecule magnet [Fe(4)(N[double bond, length as m-dash]CPh(2))(6)] with suppressed through-barrier relaxation

Reaction of FeBr(2) with 1.5 equiv. of LiN[double bond, length as m-dash]CPh(2) and 2 equiv. of Zn, in THF, results in the formation of the tetrametallic iron ketimide cluster [Fe(4)(N[double bond, length as m-dash]CPh(2))(6)] (1) in moderate yield. Formally, two Fe centers in 1 are Fe(i) and two ar...

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Publicado en:Chem Sci
Autores principales: Cook, Andrew W., Bocarsly, Joshua D., Lewis, Richard A., Touchton, Alexander J., Morochnik, Simona, Hayton, Trevor W.
Formato: Artigo
Lenguaje:Inglês
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159258/
https://ncbi.nlm.nih.gov/pubmed/34122931
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01578d
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