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Expedient synthesis of conjugated triynes via alkyne metathesis

The first synthesis of conjugated triynes by molybdenum-catalysed alkyne metathesis is reported. Strategic to the success of this approach is the utilization of sterically-hindered diynes that allowed for the site-selective alkyne metathesis to produce the desired conjugated triyne products. The ste...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Curbet, Idriss, Colombel-Rouen, Sophie, Manguin, Romane, Clermont, Anthony, Quelhas, Alexandre, Müller, Daniel S., Roisnel, Thierry, Baslé, Olivier, Trolez, Yann, Mauduit, Marc
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159245/
https://ncbi.nlm.nih.gov/pubmed/34122949
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01124j
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