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Spectroscopic investigations under whole-cell conditions provide new insight into the metal hydride chemistry of [FeFe]-hydrogenase

Hydrogenases are among the fastest H(2) evolving catalysts known to date and have been extensively studied under in vitro conditions. Here, we report the first mechanistic investigation of an [FeFe]-hydrogenase under whole-cell conditions. Functional [FeFe]-hydrogenase from the green alga Chlamydomo...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Mészáros, Lívia S., Ceccaldi, Pierre, Lorenzi, Marco, Redman, Holly J., Pfitzner, Emanuel, Heberle, Joachim, Senger, Moritz, Stripp, Sven T., Berggren, Gustav
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159234/
https://ncbi.nlm.nih.gov/pubmed/34122916
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc00512f
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