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Dialumenes – aryl vs. silyl stabilisation for small molecule activation and catalysis

Main group multiple bonds have proven their ability to act as transition metal mimics in the last few decades. However, catalytic application of these species is still in its infancy. Herein we report the second neutral NHC-stabilised dialumene species by use of a supporting aryl ligand (3). Differe...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Weetman, Catherine, Porzelt, Amelie, Bag, Prasenjit, Hanusch, Franziska, Inoue, Shigeyoshi
Format: Artigo
Sprog:Inglês
Udgivet: The Royal Society of Chemistry 2020
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159210/
https://ncbi.nlm.nih.gov/pubmed/34122939
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01561j
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