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Polarized Helical Coumarins: [1,5] Sigmatropic Rearrangement and Excited-State Intramolecular Proton Transfer

[Image: see text] The tandem process of phenol addition to a cyclic α,β-unsaturated ester followed by intramolecular transesterification and [1,5] sigmatropic rearrangement affords a series of helical coumarins based upon a previously unknown 3-amino-7-hydroxybenzo[3,4]cyclohepta[1,2-c]chromen-6-one...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Kielesiński, Łukasz, Morawski, Olaf W., Barboza, Cristina A., Gryko, Daniel T.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2021
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8154611/
https://ncbi.nlm.nih.gov/pubmed/33830755
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c02978
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