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A Monomeric Aluminum Imide (Iminoalane) with Al–N Triple-Bonding: Bonding Analysis and Dispersion Energy Stabilization
[Image: see text] The reaction of :AlAr(iPr8) (Ar(iPr8) = C(6)H-2,6-(C(6)H(2)-2,4,6-(i)Pr(3))(2)-3,5-(i)Pr(2)) with Ar(Me6)N(3) (Ar(Me6) = C(6)H(3)-2,6-(C(6)H(2)-2,4,6-Me(3))(2)) in hexanes at ambient temperature gave the aluminum imide Ar(iPr8)AlNAr(Me6) (1). Its crystal structure displayed short A...
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| Gepubliceerd in: | J Am Chem Soc |
|---|---|
| Hoofdauteurs: | , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
American Chemical
Society
2021
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| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8154528/ https://ncbi.nlm.nih.gov/pubmed/33882237 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c02463 |
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