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The (1)H NMR Spectroscopic Effect of Steric Compression Is Found in [3.3.1]Oxa- and Azabicycles and Their Analogues
[Image: see text] The through-space (1)H NMR effect of steric compression by the lone-pair electrons of O- and N-atoms is shown in synthetic [3.3.1]oxa- and azabicycles. The electrons of the compressed proton bond are pushed away by the repulsive force generated by the lone-pair electrons of the het...
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| Veröffentlicht in: | ACS Omega |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Chemical Society
2021
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8154237/ https://ncbi.nlm.nih.gov/pubmed/34056428 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.1c01093 |
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