Fluoride Ion-Initiated Decarboxylation of Silyl Alkynoates to Alkynylsilanes

[Image: see text] This communication describes the development of a metal-free catalytic decarboxylation of silyl alkynoates to alkynylsilanes. Treatment of a silyl alkynoate with a catalytic amount of tetrabutylammonium difluorotriphenylsilicate (TBAT) in N,N-dimethylformamide at 150 °C resulted in...

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Publicat a:ACS Omega
Autors principals: Kawatsu, Takahiro, Kataoka, Sho, Fukaya, Norihisa, Choi, Jun-Chul, Sato, Kazuhiko, Matsumoto, Kazuhiro
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2021
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8154224/
https://ncbi.nlm.nih.gov/pubmed/34056436
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.1c01256
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