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Strategies for remote enantiocontrol in chiral gold(iii) complexes applied to catalytic enantioselective γ,δ-Diels–Alder reactions

The use of chiral square planar gold(iii) complexes to access enantioenriched products has rarely been applied in asymmetric catalysis. In this context, we report a mechanistic and synthetic investigation into the use of N-heterocyclic (NHC) gold(iii) complexes in γ,δ-Diels–Alder reactions of 2,4-di...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Reid, Jolene P., Hu, Mingyou, Ito, Susumu, Huang, Banruo, Hong, Cynthia M., Xiang, Hengye, Sigman, Matthew S., Toste, F. Dean
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8152632/
https://ncbi.nlm.nih.gov/pubmed/34094110
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc00497a
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