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Sulfoxide-mediated oxidative cross-coupling of phenols

A metal-free, oxidative coupling of phenols with various nucleophiles, including arenes, 1,3-diketones and other phenols, is reported. Cross-coupling is mediated by a sulfoxide which inverts the reactivity of the phenol partner. Crucially, the process shows high selectivity for cross-versus homo-cou...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: He, Zhen, Perry, Gregory J. P., Procter, David J.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8150100/
https://ncbi.nlm.nih.gov/pubmed/34123295
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05668h
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