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The hunt for reactive alkynes in bio-orthogonal click reactions: insights from mechanochemical and conceptual DFT calculations

In our effort to implement the mechanical force used to activate single molecules in mechanochemistry in the context of conceptual density functional theory, we present a theoretical investigation of strained alkynes for rationalizing structural trends as well as the reactivity of cyclic alkynes tha...

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Vydáno v:Chem Sci
Hlavní autoři: Bettens, Tom, Alonso, Mercedes, Geerlings, Paul, De Proft, Frank
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society of Chemistry 2019
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8148320/
https://ncbi.nlm.nih.gov/pubmed/34123268
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04507d
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