“Broken-hearted” carbon bowl via electron shuttle reaction: energetics and electron coupling

Unprecedented one-step C[double bond, length as m-dash]C bond cleavage leading to opening of the buckybowl (π-bowl), that could provide access to carbon-rich structures with previously inaccessible topologies, is reported; highlighting the possibility to implement drastically different synthetic rou...

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Salvato in:
Dettagli Bibliografici
Pubblicato in:Chem Sci
Autori principali: Leith, Gabrielle A., Rice, Allison M., Yarbrough, Brandon J., Kittikhunnatham, Preecha, Mathur, Abhijai, Morris, Nicholas A., Francis, Megan J., Berseneva, Anna A., Dhull, Poonam, Adams, Richard D., Bobo, M. Victoria, Vannucci, Aaron A., Smith, Mark D., Garashchuk, Sophya, Shustova, Natalia B.
Natura: Artigo
Lingua:Inglês
Pubblicazione: The Royal Society of Chemistry 2021
Soggetti:
Chemistry
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8132954/
https://ncbi.nlm.nih.gov/pubmed/34040735
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06755e
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