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Free Radical Isomerizations in Acetylene Bromoboration Reaction

The experimentally motivated question of the acetylene bromoboration mechanism was addressed in order to suggest possible radical isomerization pathways for the syn-adduct. Addition–elimination mechanisms starting with a bromine radical attack at the “bromine end” or the “boron end” of the C=C bond...

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Publicat a:Molecules
Autors principals: Semrád, Hugo, Mazal, Ctibor, Munzarová, Markéta
Format: Artigo
Idioma:Inglês
Publicat: MDPI 2021
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8123272/
https://ncbi.nlm.nih.gov/pubmed/33922945
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26092501
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