The role of CuI in the siloxane-mediated Pd-catalyzed cross-coupling reactions of aryl iodides with aryl lithium reagents

Experiments indicate that a catalytic amount of CuI plays an important role in the siloxane-mediated Pd-catalyzed cross-coupling reactions with the direct use of organolithium reagents. Addition of organolithium to the siloxane transfer agent generates an organosilicon intermediate. DFT calculations...

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Bibliographic Details
Published in:Chin Chem Lett
Main Authors: Chen, Yu, Zhang, Xiao, Liu, Fang, He, Gucheng, Zhang, Ju, Houk, K.N., Smith, Amos B., Liang, Yong
Format: Artigo
Language:Inglês
Published: 2021
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8115222/
https://ncbi.nlm.nih.gov/pubmed/33994753
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.cclet.2020.05.009
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