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Enzyme-Catalyzed Azepinoindole Formation in Clavine Alkaloid Biosynthesis
(−)-Aurantioclavine (1), which contains a characteristic seven-membered ring fused to an indole ring, belongs to the azepinoindole class of fungal clavine alkaloids. Here we show that, starting from a 4-dimethylallyl-l-tryptophan precursor, a flavin adenine dinucleotide (FAD)-binding oxidase and a c...
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| Publicado no: | Org Lett |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8092377/ https://ncbi.nlm.nih.gov/pubmed/32243182 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01132 |
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