The Combination of Cross‐Hyperconjugation and σ‐Conjugation in 2,5‐Oligosilanyl Substituted Siloles

Reaction of a 2,5‐dilithiated silole with excess dichlorodimethylsilane gives the respective 2,5‐bis(chlorodimethylsilyl) substituted silole. This compound can be converted to 2,5‐bis(oligosilanyl) substituted siloles by addition of a suitable oligosilanide. In the UV spectra of the thus obtained co...

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Published in:Chemistry
Main Authors: Pöcheim, Alexander, Özpınar, Gül Altınbaş, Müller, Thomas, Baumgartner, Judith, Marschner, Christoph
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2020
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8051206/
https://ncbi.nlm.nih.gov/pubmed/32716090
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003150
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