Lone-Pair-Induced Structural Ordering in the Mixed-Valent 0D Metal-Halides Rb(23)Bi(III)(x)Sb(III)(7–x)Sb(V)(2)Cl(54) (0 ≤ x ≤ 7)

[Image: see text] Mixed-valent metal-halides containing ns(2) lone pairs may exhibit intense visible absorption, while zero-dimensional (0D) ns(2)-based metal-chlorides are generally colorless but have demonstrated promising optoelectronic properties suitable for thermometry and radiation detection....

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Detalhes bibliográficos
Publicado no:Chem Mater
Main Authors: Benin, Bogdan M., McCall, Kyle M., Wörle, Michael, Borgeaud, Dominique, Vonderach, Thomas, Sakhatskyi, Kostiantyn, Yakunin, Sergii, Günther, Detlef, Kovalenko, Maksym V.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2021
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8043103/
https://ncbi.nlm.nih.gov/pubmed/33867666
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.chemmater.0c04491
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