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State-of-the-Art Quantum Chemistry Meets Variable Reaction Coordinate Transition State Theory to Solve the Puzzling Case of the H(2)S + Cl System

[Image: see text] The atmospheric reaction of H(2)S with Cl has been reinvestigated to check if, as previously suggested, only explicit dynamical computations can lead to an accurate evaluation of the reaction rate because of strong recrossing effects and the breakdown of the variational extension o...

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Detalhes bibliográficos
Publicado no:J Chem Theory Comput
Main Authors: Lupi, Jacopo, Puzzarini, Cristina, Cavallotti, Carlo, Barone, Vincenzo
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8009477/
https://ncbi.nlm.nih.gov/pubmed/32603107
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jctc.0c00354
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