Dinuclear Lanthanide(III) Complexes from the Use of Methyl 2-Pyridyl Ketoxime: Synthetic, Structural, and Physical Studies

The first use of methyl 2-pyridyl ketoxime (mepaoH) in homometallic lanthanide(III) [Ln(III)] chemistry is described. The 1:2 reactions of Ln(NO(3))(3)·nH(2)O (Ln = Nd, Eu, Gd, Tb, Dy; n = 5, 6) and mepaoH in MeCN have provided access to complexes [Ln(2)(O(2)CMe)(4)(NO(3))(2)(mepaoH)(2)] (Ln = Nd, 1...

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Bibliographic Details
Published in:Molecules
Main Authors: Polyzou, Christina D., Nikolaou, Helen, Raptopoulou, Catherine P., Konidaris, Konstantis F., Bekiari, Vlasoula, Psycharis, Vassilis, Perlepes, Spyros P.
Format: Artigo
Language:Inglês
Published: MDPI 2021
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7999197/
https://ncbi.nlm.nih.gov/pubmed/33804026
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26061622
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